mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal Universitymrisel-96Research ArticleСтатьиRadiation-induced paramagnetic centers in nanoporous synthetic opals - a probe for near surface protonsGalukhinA.

Kremlevskaya 18, Kazan 420008

OsinY.

Kremlevskaya 18, Kazan 420008

RodionovA.

Kremlevskaya 18, Kazan 420008

MaminG.

Kremlevskaya 18, Kazan 420008

GafurovM.

Kremlevskaya 18, Kazan 420008

OrlinskiiS.

Kremlevskaya 18, Kazan 420008

sergei.orlinskii@kpfu.ruKazan Federal UniversityRussian Federation20181012201820218203 (5 pp.)Copyright © Galukhin A., Osin Y., Rodionov A., Mamin G., Gafurov M., Orlinskii S., 20242024Galukhin A., Osin Y., Rodionov A., Mamin G., Gafurov M., Orlinskii S.Galukhin A., Osin Y., Rodionov A., Mamin G., Gafurov M., Orlinskii S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/96

The studies of chemical processes in spatially confined conditions are of interest from the fundamental and industrial points of view. By means of the W-band EPR and 1H Mims electron nuclear double resonance (ENDOR) we show that the radiation-induced paramagnetic centers (E') in the synthetic nanoporous silica opals could be used as sensitive probes to investigate the surface modification and, potentially, reactions of polymerization in the confined by opal pores.

poresopal filmshydrogen bondingENDOREPRThe work is financially supported by the Russian Science Foundation, Project # 18-13-00149.ReferencesAlcoutlabi M., McKenna G.B. J. Phys.: Condens. Matter 17, R461 (2005)Alcoutlabi M., McKenna G.B. J. Phys.: Condens. Matter 17, R461 (2005)Xu B., Di X., McKenna G.B. J. Therm. Anal. Calorim. 113, 539 (2013)Xu B., Di X., McKenna G.B. J. Therm. Anal. Calorim. 113, 539 (2013)Wang L.P., Li Q.F., Wang C., Lan X.Z. J. Phys. Chem. C 118, 18177 (2014)Wang L.P., Li Q.F., Wang C., Lan X.Z. J. Phys. Chem. C 118, 18177 (2014)Christenson H.K. J. Phys.: Condens. Matter 13, R95 (2001)Christenson H.K. J. Phys.: Condens. Matter 13, R95 (2001)Zhao H.Y., Simon S.L. Polymer 66, 173 (2015)Zhao H.Y., Simon S.L. Polymer 66, 173 (2015)Begum F., Zhao H.Y., Simon S.L. Polymer 53, 3238 (2012)Begum F., Zhao H.Y., Simon S.L. Polymer 53, 3238 (2012)Giussi M., Blaszczyk-Lezak I., Cortizo M.S., Mijangos C. Polymer 54, 6886 (2013)Giussi M., Blaszczyk-Lezak I., Cortizo M.S., Mijangos C. Polymer 54, 6886 (2013)Lopez E, Simon S.L. Macromolecules 48, 4692 (2015)Lopez E, Simon S.L. Macromolecules 48, 4692 (2015)Koh Y.P., Li Q., Simon S.L. Thermochim. Acta 492, 45 (2009)Koh Y.P., Li Q., Simon S.L. Thermochim. Acta 492, 45 (2009)Koh Y.P., Simon S.L. J. Phys. Chem. B 115, 952 (2011)Koh Y.P., Simon S.L. J. Phys. Chem. B 115, 952 (2011)Newton M.R., Bohaty A.K., White H.S., Zharov I. J. Am. Chem. Soc. 127, 7268 (2005)Newton M.R., Bohaty A.K., White H.S., Zharov I. J. Am. Chem. Soc. 127, 7268 (2005)Yavkin B.V., Mamin G.V., Gafurov M.R., Orlinskii S.B. Magn. Reson. Solids 17, 15101 (2015)Yavkin B.V., Mamin G.V., Gafurov M.R., Orlinskii S.B. Magn. Reson. Solids 17, 15101 (2015)Kratochvílová I., Šebera J., Ashcheulov P., Golan M., Ledvina M., Míčová J., Mravec F., Kovalenko A., Zverev D., Yavkin B., Orlinskii S., Zalis S., Fiserova A., Richter J., Sefs L., Turanek J. J. Phys. Chem. C 118, 25245 (2014)Kratochvílová I., Šebera J., Ashcheulov P., Golan M., Ledvina M., Míčová J., Mravec F., Kovalenko A., Zverev D., Yavkin B., Orlinskii S., Zalis S., Fiserova A., Richter J., Sefs L., Turanek J. J. Phys. Chem. C 118, 25245 (2014)Mamin G.V., Rodionov A.A., Tagirov M.S., Tayurskii D.A., Mulders N. JETP Lett. 88, 244 (2008)Mamin G.V., Rodionov A.A., Tagirov M.S., Tayurskii D.A., Mulders N. JETP Lett. 88, 244 (2008)Mamin G.V., Orlinskii S.B., Rodionov A.A., Tagirov M.S. JETP Lett. 102, 628 (2015)Mamin G.V., Orlinskii S.B., Rodionov A.A., Tagirov M.S. JETP Lett. 102, 628 (2015)Aminov L.K., Kurkin I.N., Lukoyanov D.A., Chernov K.P. Phys. Solid State 39, 1184 (1997)Aminov L.K., Kurkin I.N., Lukoyanov D.A., Chernov K.P. Phys. Solid State 39, 1184 (1997)Mukhambetov I.N., Lamberov A.A., Yavkin B.V., Gafurov M.R., Mamin G.V., Orlinskii S.B. J. Phys. Chem. C 118, 14998 (2014)Mukhambetov I.N., Lamberov A.A., Yavkin B.V., Gafurov M.R., Mamin G.V., Orlinskii S.B. J. Phys. Chem. C 118, 14998 (2014)Gafurov M.R., Mukhambetov I.N., Yavkin B.V., Mamin G.V., Lamberov A.A., Orlinskii S.B. J. Phys. Chem. C 119, 27410 (2015)Gafurov M.R., Mukhambetov I.N., Yavkin B.V., Mamin G.V., Lamberov A.A., Orlinskii S.B. J. Phys. Chem. C 119, 27410 (2015)Gafurov M., Biktagirov T., Yavkin B., Mamin G., Filippov Y., Klimashina E., Putlayev V., Orlinskii S. JETP Lett. 99, 196 (2014)Gafurov M., Biktagirov T., Yavkin B., Mamin G., Filippov Y., Klimashina E., Putlayev V., Orlinskii S. JETP Lett. 99, 196 (2014)Gafurov M., Biktagirov T., Mamin G., Orlinskii S. Appl. Magn. Reson. 45, 1189 (2014)Gafurov M., Biktagirov T., Mamin G., Orlinskii S. Appl. Magn. Reson. 45, 1189 (2014)Galukhin A., Bolmatenkov D., Osin Y. RSC Adv. 8, 18110 (2018)Galukhin A., Bolmatenkov D., Osin Y. RSC Adv. 8, 18110 (2018)Giesche H. J. Eur. Ceram. Soc. 14, 205 (1994)Giesche H. J. Eur. Ceram. Soc. 14, 205 (1994)Wong S., Kitaev V., Ozin G.A. J. Am. Chem. Soc. 125, 15589 (2003)Wong S., Kitaev V., Ozin G.A. J. Am. Chem. Soc. 125, 15589 (2003)Yavkin B.V., Mamin G.V., Orlinskii S.B., Gafurov M.R., Salakhov M.K., Biktagirov T.B., Klimashina E.S., Pultlayev V.I., Tretyakov Yu.D., Silkin N.I. Phys. Chem. Chem. Phys. 14, 2246 (2012)Yavkin B.V., Mamin G.V., Orlinskii S.B., Gafurov M.R., Salakhov M.K., Biktagirov T.B., Klimashina E.S., Pultlayev V.I., Tretyakov Yu.D., Silkin N.I. Phys. Chem. Chem. Phys. 14, 2246 (2012)Biktagirov T., Gafurov M., Mamin G., Gracheva I., Galukhin A., Orlinskii S. Energy Fuels 31, 1243 (2017)Biktagirov T., Gafurov M., Mamin G., Gracheva I., Galukhin A., Orlinskii S. Energy Fuels 31, 1243 (2017)Alessi A., Agnello S., Buscarino G., PanY., Mashkovtsev R.I. Chapter 7. EPR on Radiation-Induced Defects in SiO2. In Lund A., Shiotani M. Applications of EPR in Radiation Research (Springer: Cham, 2014) 255-295Alessi A., Agnello S., Buscarino G., PanY., Mashkovtsev R.I. Chapter 7. EPR on Radiation-Induced Defects in SiO2. In Lund A., Shiotani M. Applications of EPR in Radiation Research (Springer: Cham, 2014) 255-295Mashkovtsev R.I., Pan Y. Nature of Paramagnetic Defects in α-quartz: Progresses in the First Decade of the 21st Century. In Novak B., Marek P. New Developments in Quartz Research: Varieties, Crystal Chemistry and Uses in Technology (Nova: NY, 2013) 65-104Mashkovtsev R.I., Pan Y. Nature of Paramagnetic Defects in α-quartz: Progresses in the First Decade of the 21st Century. In Novak B., Marek P. New Developments in Quartz Research: Varieties, Crystal Chemistry and Uses in Technology (Nova: NY, 2013) 65-104Perlson B.D., Weil J.A. Can. J. Phys. 86, 871 (2008)Perlson B.D., Weil J.A. Can. J. Phys. 86, 871 (2008)Feigl F.J., Anderson J.H. J. Phys. Chem. Solids 31, 575 (1970)Feigl F.J., Anderson J.H. J. Phys. Chem. Solids 31, 575 (1970)Gizatullin B., Gafurov M., Rodionov A., Mamin G., Mattea C., Stapf S., Orlinskii S. Energy Fuels 32, 11261 (2018)Gizatullin B., Gafurov M., Rodionov A., Mamin G., Mattea C., Stapf S., Orlinskii S. Energy Fuels 32, 11261 (2018)

The authors declare that there are no conflicts of interest present.