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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">mrisel</journal-id><journal-title-group><journal-title xml:lang="en">Magnetic Resonance in Solids</journal-title><trans-title-group xml:lang="ru"><trans-title>Magnetic Resonance in Solids</trans-title></trans-title-group></journal-title-group><issn pub-type="epub">2072-5981</issn><publisher><publisher-name>Kazan Federal University</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.26907/mrsej-19408</article-id><article-id custom-type="elpub" pub-id-type="custom">mrisel-70</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>To the structure of the trigonal center of Yb3+ ion in hexagonal perovskite crystal RbMgF3</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Leushin</surname><given-names>A. M.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kremlevskaya 18, Kazan 420008</p></bio><email xlink:type="simple">amleushin@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>Kazan Federal University</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2019</year></pub-date><pub-date pub-type="epub"><day>06</day><month>06</month><year>2019</year></pub-date><volume>21</volume><issue>4</issue><issue-title>SPECIAL ISSUE dedicated to Boris Z. Malkin's 80th birthday</issue-title><elocation-id>19408 (6 pp.)</elocation-id><permissions><copyright-statement>Copyright &amp;#x00A9; Leushin A.M., 2024</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="ru">Leushin A.M.</copyright-holder><copyright-holder xml:lang="en">Leushin A.M.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.mrsej.ru/jour/article/view/70">https://www.mrsej.ru/jour/article/view/70</self-uri><abstract><p>EPR and optical spectra are used for the analysis of distortions of a crystal lattice in the vicinity of an impurity ion Yb3+ of trigonal symmetry in RbMgF3 crystal. Within the framework of the superposition model, it is established that three F− ions of the nearest-neighboring octahedron, located symmetrically along the threefold axis of the trigonal center, move away from the impurity ion and have considerable angular deviations from the symmetry axis of the center. The next three F− ions, which enter the other octahedra, shift towards the paramagnetic ion and, on the contrary, come a bit closer to the axis.</p></abstract><kwd-group xml:lang="en"><kwd>perovskite RbMgF3</kwd><kwd>crystal field</kwd><kwd>syperposition model</kwd><kwd>rare earth</kwd></kwd-group><funding-group><funding-statement xml:lang="en">This study was supported by the subsidy allocated to Kazan Federal University for the state assignment in the sphere of scientific activities (project 3.672.2017/8.9).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Falin M.L., Latypov V.A., Leushin A.M., Safiullin G.M. J. Alloys Compd. 735, 23 (2018)</mixed-citation><mixed-citation xml:lang="en">Falin M.L., Latypov V.A., Leushin A.M., Safiullin G.M. J. Alloys Compd. 735, 23 (2018)</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Dance J.M., Kerkouri C.R., Tressaud A. Mater. Res. Bull. 14, 869 (1979)</mixed-citation><mixed-citation xml:lang="en">Dance J.M., Kerkouri C.R., Tressaud A. Mater. Res. Bull. 14, 869 (1979)</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Kerkouri C.R., Dance J.M. Mater. Res. Bull. 19, 751 (1984)</mixed-citation><mixed-citation xml:lang="en">Kerkouri C.R., Dance J.M. Mater. Res. Bull. 19, 751 (1984)</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Yeung Y.Y., Rudowicz C. Computers Chem. 16, 207 (1992)</mixed-citation><mixed-citation xml:lang="en">Yeung Y.Y., Rudowicz C. Computers Chem. 16, 207 (1992)</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Schrama A.H.M. Physica 66, 131 (1973)</mixed-citation><mixed-citation xml:lang="en">Schrama A.H.M. Physica 66, 131 (1973)</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Newman D.J. Adv. Phys. 20, 197 (1971)</mixed-citation><mixed-citation xml:lang="en">Newman D.J. Adv. Phys. 20, 197 (1971)</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Newman D.J. Aust. J. Phys. 31, 79 (1978)</mixed-citation><mixed-citation xml:lang="en">Newman D.J. Aust. J. Phys. 31, 79 (1978)</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Newman D.J., Ng B. Rep. Progr. Phys. 52, 699 (1989)</mixed-citation><mixed-citation xml:lang="en">Newman D.J., Ng B. Rep. Progr. Phys. 52, 699 (1989)</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Newman D.J., Ng B. Superposition Model, in Crystal Field Handbook, edited by D.J. Newman, B. Ng, Cambridge University Press (2000), pp. 83-119</mixed-citation><mixed-citation xml:lang="en">Newman D.J., Ng B. Superposition Model, in Crystal Field Handbook, edited by D.J. Newman, B. Ng, Cambridge University Press (2000), pp. 83-119</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Andrut M., Wildner M., Rudowicz C. EMU Notes Mineralogy 6, 145 (2004)</mixed-citation><mixed-citation xml:lang="en">Andrut M., Wildner M., Rudowicz C. EMU Notes Mineralogy 6, 145 (2004)</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Leushin A.M. Phys. Solid State 55, 2558 (2013)</mixed-citation><mixed-citation xml:lang="en">Leushin A.M. Phys. Solid State 55, 2558 (2013)</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Aleonard S., Pouzet C. J. Appl. Crystallogr. 1, 113 (1968)</mixed-citation><mixed-citation xml:lang="en">Aleonard S., Pouzet C. J. Appl. Crystallogr. 1, 113 (1968)</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
