mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal University10.26907/mrsej-25309mrisel-294Research ArticleСтатьиLow-field 129Xe NMR of liquid Xenon near the triple point: experimental design, relaxation measurements, and preliminary applications to porous mediaSannikovK. O.

Kazan 420008

KirOSannikov@kpfu.ruKlochkovA. V.

Kazan 420008

Institute of Physics, Kazan Federal UniversityRussian Federation20253012202527325309 (10 pp.)Copyright © Sannikov K.O., Klochkov A.V., 20252025Sannikov K.O., Klochkov A.V.Sannikov K.O., Klochkov A.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/294

In this article, the capabilities of using low-field NMR of liquid 129Xe near triple point in the study of porous media were demonstrated. The possibility of detecting the NMR signal of Xenon with natural isotopic composition and Boltzmann equilibrium spin polarization in the liquid and solid phases was explored. The problems encountered during the planning and conducting the experiments, along with their solutions, are presented. Key issues included low sensitivity, particularly in magnetic fields up to 1T; difficulties in filling the experimental cell with liquid Xenon; the critical need to control the temperature gradient along the NMR probe axis and prevent capillary blockage; control of the solid-to-liquid transition; RF-noise from the electrical leads. As a result, spin-lattice relaxation times (T1) of bulk Xenon were measured and the spin-spin relaxation times (T2) of bulk Xenon were estimated. Some of preliminary results on 129Xe NMR in porous media are presented.

NMRXenon129Xelow temperaturesporous mediaphase transitionThis work was financially supported by the subsidy of Ministry of Science and Higher Education of the Russian Federation to Kazan Federal University (FZSM-2023-0012).ReferencesBoventi M., Mauri M., Simonutti R. Applied Sciences 12, 3152 (2022).Boventi M., Mauri M., Simonutti R. Applied Sciences 12, 3152 (2022).Stanislavovas A., Kuzmin V., Safiullin K., Alakshin E., Klochkov A., Kutuzov M., Tagirov M. Journal of Physics: Condensed Matter 33, 195805 (2021).Stanislavovas A., Kuzmin V., Safiullin K., Alakshin E., Klochkov A., Kutuzov M., Tagirov M. Journal of Physics: Condensed Matter 33, 195805 (2021).Kuzmin V., Safiullin K., Dolgorukov G., Stanislavovas A., Alakshin E., Safin T., Yavkin B., Orlinskii S., Kiiamiv A., Presnyakov M., Tagirov M. Physical Chemistry Chemical Physics 20, 1476 (2018).Kuzmin V., Safiullin K., Dolgorukov G., Stanislavovas A., Alakshin E., Safin T., Yavkin B., Orlinskii S., Kiiamiv A., Presnyakov M., Tagirov M. Physical Chemistry Chemical Physics 20, 1476 (2018).Safiullin K., Kuzmin V., Bogaychuk A., Alakshin E., González L., Kondratyeva E., Dolgorukov G., Gafurov M., Klochkov A., Tagirov M. Journal of Petroleum Science and Engineering 210, 110010 (2022).Safiullin K., Kuzmin V., Bogaychuk A., Alakshin E., González L., Kondratyeva E., Dolgorukov G., Gafurov M., Klochkov A., Tagirov M. Journal of Petroleum Science and Engineering 210, 110010 (2022).Gazizulin R. R., Klochkov A. V., Kuzmin V. V., Safiullin K. R.,Tagirov M. S., Yudin A. N., Izotov V. G., Sitdikova L. M. Applied Magnetic Resonance 38, 271 (2010).Gazizulin R. R., Klochkov A. V., Kuzmin V. V., Safiullin K. R.,Tagirov M. S., Yudin A. N., Izotov V. G., Sitdikova L. M. Applied Magnetic Resonance 38, 271 (2010).Proctor W. G., Yu F. C. Physical Review 78, 471 (1950).Proctor W. G., Yu F. C. Physical Review 78, 471 (1950).Proctor W. G., Yu F. C. Physical Review 81, 20 (1951).Proctor W. G., Yu F. C. Physical Review 81, 20 (1951).Ito T., Fraissard J. The Journal of Chemical Physics 76, 5225 (1982).Ito T., Fraissard J. The Journal of Chemical Physics 76, 5225 (1982).Raftery D., Long H., Meersmann T., Grandinetti P. J., Reven L., Pines A. Physical Review Letters 66, 584 (1991).Raftery D., Long H., Meersmann T., Grandinetti P. J., Reven L., Pines A. Physical Review Letters 66, 584 (1991).Wisser D., Hartmann M. Advanced Materials Interfaces 8, 2001266 (2021).Wisser D., Hartmann M. Advanced Materials Interfaces 8, 2001266 (2021).Weiland E., Springuel-Huet M. A., Nossov A., Gedeon A. Advanced Materials Interfaces 225, 41 (2016).Weiland E., Springuel-Huet M. A., Nossov A., Gedeon A. Advanced Materials Interfaces 225, 41 (2016).Cho G., Moran L. B., Yesinowski J. P. Applied Magnetic Resonance 8, 549 (1995).Cho G., Moran L. B., Yesinowski J. P. Applied Magnetic Resonance 8, 549 (1995).Li L., Guo L., Zhang Z., Yang Q., Yang Y., Bao Z., Ren Q., Li J. Journal of the American Chemical Society 141, 9358 (2019).Li L., Guo L., Zhang Z., Yang Q., Yang Y., Bao Z., Ren Q., Li J. Journal of the American Chemical Society 141, 9358 (2019).Alakshin E. M., Gazizulin R. R., Klochkov A. V., Kuzmin V. V., Sabitova A. M., Safin T. R., Tagirov M. S. Magnetic Resonance in Solids. Electronic Journal 15, 13104 (2013).Alakshin E. M., Gazizulin R. R., Klochkov A. V., Kuzmin V. V., Sabitova A. M., Safin T. R., Tagirov M. S. Magnetic Resonance in Solids. Electronic Journal 15, 13104 (2013).Dolgorukov G. A., Kuzmin V. V., Bogaychuk A. V., Alakshin E. M., Safiullin K. R., Klochkov A. V., Tagirov M. S. Magnetic Resonance in Solids. Electronic Journal 20, 18206 (2018).Dolgorukov G. A., Kuzmin V. V., Bogaychuk A. V., Alakshin E. M., Safiullin K. R., Klochkov A. V., Tagirov M. S. Magnetic Resonance in Solids. Electronic Journal 20, 18206 (2018).Moudrakovski I. L., Breeze S. R., Simard B., Ratcliffe C. I., Ripmeester J. A., Seideman T., Tse J. S., Santyr G. The Journal of Chemical Physics 114, 2173 (2001).Moudrakovski I. L., Breeze S. R., Simard B., Ratcliffe C. I., Ripmeester J. A., Seideman T., Tse J. S., Santyr G. The Journal of Chemical Physics 114, 2173 (2001).Xenon - the NIST WebBook.Xenon - the NIST WebBook.Cherubini A., Bifone A. Progress in Nuclear Magnetic Resonance Spectroscopy 42, 1 (2003).Cherubini A., Bifone A. Progress in Nuclear Magnetic Resonance Spectroscopy 42, 1 (2003).Hunt E. R., Carr H. Y. Physical Review 130, 2302 (1963).Hunt E. R., Carr H. Y. Physical Review 130, 2302 (1963).Sauer K. L., Fitzgerald R. J., Happer W. Chemical physics letters 277, 153 (1997).Sauer K. L., Fitzgerald R. J., Happer W. Chemical physics letters 277, 153 (1997).Yen W. M., Norberg R. E. Physical Review 131, 269 (1963).Yen W. M., Norberg R. E. Physical Review 131, 269 (1963).

The authors declare that there are no conflicts of interest present.