mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal University10.26907/mrsej-24217mrisel-270Research ArticleСтатьиParamagnetic impurity centers of Fe3+ in the silicon positions of yttrium orthosilicateVazheninV. A.

Yekaterinburg 620002

Vladimir.Vazhenin@urfu.ruArtyomovM. Yu.

Yekaterinburg 620002

PotapovA. P.

Yekaterinburg 620002

SubbotinK. A.

Moscow 119991

LisD. A.

Moscow 119991

PavlovS. K.

Moscow 119991

FokinA. V.

Yekaterinburg 620002

VolkovP. A.

Moscow 123182

Ural Federal UniversityRussian FederationProkhorov General Physics Institute of Russian Academy of SciencesRussian FederationNational Research Centre “Kurchatov Institute”Russian Federation202429082024262SPECIAL ISSUE dedicated to Boris Z. Malkin's 85th birthday24217 (11 pp.)Copyright © Vazhenin V.A., Artyomov M.Y., Potapov A.P., Subbotin K.A., Lis D.A., Pavlov S.K., Fokin A.V., Volkov P.A., 20242024Vazhenin V.A., Artyomov M.Y., Potapov A.P., Subbotin K.A., Lis D.A., Pavlov S.K., Fokin A.V., Volkov P.A.Vazhenin V.A., Artyomov M.Y., Potapov A.P., Subbotin K.A., Lis D.A., Pavlov S.K., Fokin A.V., Volkov P.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/270

In the Y2SiO5 single crystal doped with iron, transitions of three triclinic Fe3+ centers localized in silicon positions were detected near (g = 4.3). The positions of these transitions weakly depend on the orientation of the magnetic field. The orientation behavior of other transitions of these centers has been studied. The parameters of the constructed spin Hamiltonians of two of them in the main axes satisfy the conditions: (b20 ≡ D) is close to (b22 ≡ 3E) while (b20 ≫ gβB). These centers can be attributed to Fe3+ ions localized in silicon positions and compensated for both locally and non-locally by oxygen vacancies.

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The authors declare that there are no conflicts of interest present.