mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal University10.26907/mrsej-24210mrisel-263Research ArticleСтатьиErbium luminescent probe in a GdFe3(BO3)4 single crystal: phase transitions and temperature measurementsPopovaM. N.

Troitsk 108840

popova@isan.troitsk.ruDiabM.

Troitsk 108840

Dolgoprudnyi 141700

BoldyrevK. N.

Troitsk 108840

Institute of Spectroscopy, Russian Academy of SciencesRussian FederationInstitute of Spectroscopy, Russian Academy of Sciences; Moscow Institute of Physics and Technology (National Research University)Russian Federation202429082024262SPECIAL ISSUE dedicated to Boris Z. Malkin's 85th birthday24210 (7 pp.)Copyright © Popova M.N., Diab M., Boldyrev K.N., 20242024Popova M.N., Diab M., Boldyrev K.N.Popova M.N., Diab M., Boldyrev K.N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/263

In this study, we demonstrate a detection of three phase transitions in a GdFe3 (BO3 )4 sin­gle crystal using the photoluminescence of Er3+ ions introduced in a small amount into the crystal. A first-order R32^P3121 structural phase transition is seen as a sharp spectral line shift at Ts = 127 K. Magnetic ordering of the iron subsystem at TN = 37 K causes a splitting of Er3+ Kramers doublets and is detected by a splitting of spectral lines. A first-order spin­reorientation phase transition at TR = 9 K manifests itself in a sharp change of the line splitting pattern. A comparison of the measured ratio of luminescence line intensities with the ratio of the Boltzmann populations of the involved levels is proposed to control the possible heating of the GdFe3(BO3)4:Er3+ sample by exciting radiation.

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The authors declare that there are no conflicts of interest present.