mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal University10.26907/mrsej-24207mrisel-260Research ArticleСтатьиRabi oscillations and ENDOR study of trivalent gadolinium ion in LiYF4 crystalMaminG. V.

Kazan 420008

MurzakhanovF. F.

Kazan 420008

KurkinI. N.

Kazan 420008

GafurovM. R.

Kazan 420008

BaibekovE. I.

Kazan 420008

edbaibek@gmail.comKazan Federal UniversityRussian Federation202429082024262SPECIAL ISSUE dedicated to Boris Z. Malkin's 85th birthday24207 (6 pp.)Copyright © Mamin G.V., Murzakhanov F.F., Kurkin I.N., Gafurov M.R., Baibekov E.I., 20242024Mamin G.V., Murzakhanov F.F., Kurkin I.N., Gafurov M.R., Baibekov E.I.Mamin G.V., Murzakhanov F.F., Kurkin I.N., Gafurov M.R., Baibekov E.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/260

We demonstrate coherent electron and electron-nuclear spin manipulations using the impurity trivalent gadolinium ion and the nearby 7Li and 19F nuclei incorporated in the LiYF4 host crystal. In particular, we present the electronic Rabi oscillations corresponding to -1/2 ⇔ 1/2 and 5/2 ⇔ 7/2 transitions between the projections of the Gd3+ spin S=7/2 of the lowest manifold 8S7/2, together with the spin-lattice and spin-spin coherence times of these transitions. High-resolution pulsed electron-nuclear double resonance spectra involving -1/2 ⇔ 1/2 or 5/2 ⇔ 7/2 gadolinium transitions and either 7Li (nuclear spin I=3/2) or 19F (I=1/2) nuclear spin transition are obtained. The results suggest that the particular system can be potentially used for the implementation of hybrid quantum calculations utilizing both the electronic high-spin gadolinium states and the nuclear spin states of the adjacent ions.

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The authors declare that there are no conflicts of interest present.