mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal University10.26907/mrsej-24103mrisel-242Research ArticleСтатьиSynthesis and study of the cerium doped hydroxyapatite powdersNikitinaY. O.

Moscow 119334

PetrakovaN. V.

Moscow 119334

MaksimenkoE. I.

Moscow 119334

ChizhevskayaS. V.

Moscow 125480

AndreevS. M.

Peterhof 198504

SadovnikovaM. A.

Kazan 420008

MurzakhanovF. F.

Kazan 420008

murzakhanov.fadis@yandex.ruMaminG. V.

Kazan 420008

GafurovM. R.

Kazan 420008

KomlevV. S.

Moscow 119334

A.A. Baikov Institute of Metallurgy and Materials Science RASRussian FederationD. Mendeleyev University of Chemical Technology of RussiaRussian FederationSt. Petersburg State UniversityRussian FederationKazan Federal UniversityRussian Federation202419042023261SPECIAL ISSUE dedicated to Boris I. Kochelaev's 90th birthday24103 (11 pp.)Copyright © Nikitina Y.O., Petrakova N.V., Maksimenko E.I., Chizhevskaya S.V., Andreev S.M., Sadovnikova M.A., Murzakhanov F.F., Mamin G.V., Gafurov M.R., Komlev V.S., 20242024Nikitina Y.O., Petrakova N.V., Maksimenko E.I., Chizhevskaya S.V., Andreev S.M., Sadovnikova M.A., Murzakhanov F.F., Mamin G.V., Gafurov M.R., Komlev V.S.Nikitina Y.O., Petrakova N.V., Maksimenko E.I., Chizhevskaya S.V., Andreev S.M., Sadovnikova M.A., Murzakhanov F.F., Mamin G.V., Gafurov M.R., Komlev V.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/242

Hydroxyapatite (HAp) is an attractive material for creating biocompatible implants owing to its osteoregenerative properties, elemental and phase similarity to bone tissue. The flexible structure of the material allows the introduction of ionic impurities to improve physicochemical and biological characteristics while maintaining the space symmetry group. Rare earth ions are a new step in improving compounds to create luminescent bioimaging agent for application in diagnostics imaging medicine. Nanosized powder of HAp doped with cerium ions (Ce-HAp) was obtained in order to study the impurity localization and its oxidizing state with conventional and pulsed electron paramagnetic resonance (EPR) at X-band. Undoped and doped HAp powders were synthesized via precipitation technique. It was revealed, that Ce-HAp powders after synthesis and heating exhibit luminescence in visible wavelength range (380 and 420 nm) that confirms the presence of Ce3+ in HAp structure. Heating of Ce-HAp in the air atmosphere results in formation of CeO2 with low intensity of luminescence. EPR spectra of the doped sample confirms the Ce3+ incorporation into HAp structure. The powder-like EPR lineshape for the obtained powders can be simulated with g∥ = 3.47 and g⊥ = 0.51.

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The authors declare that there are no conflicts of interest present.