mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal University10.26907/mrsej-23202mrisel-23Research ArticleСтатьиOrdered state of the intrinstic two-component magnetoelectric material Li2CuZrO4 according to 7Li NMR dataVavilovaE. L.

Kazan

jenia.vavilova@gmail.comZavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RASRussian Federation20231212202325223202 (9 pp.)Copyright © Vavilova E.L., 20232023Vavilova E.L.Vavilova E.L.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/23

The magnetic system of the Li2CuCrO4 compound is characterized by the formation of helical spin structures in CuO2 chains due to strong frustrations of the exchange interaction. The double position of lithium ions determines the existence of the dielectric glass state at T<=70 K. In this work, using the NMR technique, we found the activation energy of the dipole glass system Ea = 101 K and determined the type of helicoidal copper spin structure as a "screw". It was demonstrated how the high-temperature interaction of strongly correlated spin and dielectric subsystems in this compound paradoxically prevents the appearance of multiferroic behavior in the ordered phase

low-dimensional magnetismfrustrationspin chainsnuclear magnetic resonancemagnetizationmagnetoelectric interactionsThe work was supported by the budget financing of Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RASReferencesGippius A., Moskvin A., Morozova E., Okhotnikov K., J. Exp. Theor. Phys. 105, 86–89 (2007).Gippius A., Moskvin A., Morozova E., Okhotnikov K., J. Exp. Theor. Phys. 105, 86–89 (2007).Dai D., Koo H.-J., Whangbo M.-H., Inorg. Chem. 43, 4026–4035 (2004).Dai D., Koo H.-J., Whangbo M.-H., Inorg. Chem. 43, 4026–4035 (2004).Gibson B., Kremer R., Prokofiev A., Assmus W., McIntyre G., Physica B: Condensed Matter 350, E253 (2004), supplement.Gibson B., Kremer R., Prokofiev A., Assmus W., McIntyre G., Physica B: Condensed Matter 350, E253 (2004), supplement.Dutton S. E., Kumar M., Mourigal M., Soos Z. G., Wen J.-J., Broholm C. L., Andersen N. H., Huang Q., Zbiri M., Toft-Petersen R., Cava R. J., Phys. Rev. Lett. 108, 187206 (2012).Dutton S. E., Kumar M., Mourigal M., Soos Z. G., Wen J.-J., Broholm C. L., Andersen N. H., Huang Q., Zbiri M., Toft-Petersen R., Cava R. J., Phys. Rev. Lett. 108, 187206 (2012).Grafe H.-J., Nishimoto S., Iakovleva M., Vavilova E., Spillecke L., Alfonsov A., Sturza M.- I., Wurmehl S., Nojiri H., Rosner H., Richter J., R¨oßler U. K., Drechsler S.-L., Kataev V., B¨uchner B., Scientific Reports 7, 6720 (2017).Grafe H.-J., Nishimoto S., Iakovleva M., Vavilova E., Spillecke L., Alfonsov A., Sturza M.- I., Wurmehl S., Nojiri H., Rosner H., Richter J., R¨oßler U. K., Drechsler S.-L., Kataev V., B¨uchner B., Scientific Reports 7, 6720 (2017).Onoda S., Nagaosa N., Phys. Rev. Lett. 99, 027206 (2007).Onoda S., Nagaosa N., Phys. Rev. Lett. 99, 027206 (2007).Schmitt M., M´alek J., Drechsler S.-L., Rosner H., Phys. Rev. B. 80, 205111 (2009).Schmitt M., M´alek J., Drechsler S.-L., Rosner H., Phys. Rev. B. 80, 205111 (2009).Vavilova E., Moskvin A. S., Arango Y. C., Sotnikov A., Drechsler S.-L., Klingeler R., Volkova O., Vasiliev A., Kataev V., B¨uchner B., Europhys. Lett. 88, 27001 (2009).Vavilova E., Moskvin A. S., Arango Y. C., Sotnikov A., Drechsler S.-L., Klingeler R., Volkova O., Vasiliev A., Kataev V., B¨uchner B., Europhys. Lett. 88, 27001 (2009).Moskvin A. S., Vavilova E., Drechsler S.-L., Kataev V., B¨uchner B., Phys. Rev. B. 87, 054405 (2013).Moskvin A. S., Vavilova E., Drechsler S.-L., Kataev V., B¨uchner B., Phys. Rev. B. 87, 054405 (2013).Orlova A., Green E., Law J., Gorbunov D., Chanda G., Kr¨amer S., Horvati´c M., Kremer R., Wosnitza J., Rikken G., Phys. Rev. Lett. 118, 247201 (2017).Orlova A., Green E., Law J., Gorbunov D., Chanda G., Kr¨amer S., Horvati´c M., Kremer R., Wosnitza J., Rikken G., Phys. Rev. Lett. 118, 247201 (2017).B¨uttgen N., Kraetschmer W., Svistov L. E., Prozorova L. A., Prokofiev A., Phys. Rev. B. 81, 052403 (2010).B¨uttgen N., Kraetschmer W., Svistov L. E., Prozorova L. A., Prokofiev A., Phys. Rev. B. 81, 052403 (2010).Vavilova E., Nishimoto S., Salikhov T., Vasilchikova T., Nalbandyan V., Vasiliev A., Zvereva E., Phys. Rev. B. 103, 094415 (2021).Vavilova E., Nishimoto S., Salikhov T., Vasilchikova T., Nalbandyan V., Vasiliev A., Zvereva E., Phys. Rev. B. 103, 094415 (2021).Grey C. P., Dupre N., Chem. Rev. 104, 4493–4512 (2004).Grey C. P., Dupre N., Chem. Rev. 104, 4493–4512 (2004).K¨ohler T., Hanzig J., Koroteev V., Vyalikh A., Zakharchenko T., Itkis D. M., Krajnc A., Mali G., Bulusheva L. G., Okotrub A. V., Yashina L. V., Velasco-Velez J. J., Usachov D. Y., Vyalikh D. V., St¨ocker H., Avdeev M. V., Bobrikov I. A., Petrenko V. I., Funke C., Chakravadhanula V. S. K., St¨ober M., Zosel J., Cherkouk C., M¨unchgesang W., Langklotz U., Berendes E., Socher S., Potthoff U., “Chapter 5. Characterization methods,” in Electrochemical Storage Materials. From Crystallography to Manufacturing Technology, edited by Meyer D. C., Leisegang T., Zschornak M., St¨ocker H. (De Gruyter, Berlin, Boston, 2018) pp. 261–408.K¨ohler T., Hanzig J., Koroteev V., Vyalikh A., Zakharchenko T., Itkis D. M., Krajnc A., Mali G., Bulusheva L. G., Okotrub A. V., Yashina L. V., Velasco-Velez J. J., Usachov D. Y., Vyalikh D. V., St¨ocker H., Avdeev M. V., Bobrikov I. A., Petrenko V. I., Funke C., Chakravadhanula V. S. K., St¨ober M., Zosel J., Cherkouk C., M¨unchgesang W., Langklotz U., Berendes E., Socher S., Potthoff U., “Chapter 5. Characterization methods,” in Electrochemical Storage Materials. From Crystallography to Manufacturing Technology, edited by Meyer D. C., Leisegang T., Zschornak M., St¨ocker H. (De Gruyter, Berlin, Boston, 2018) pp. 261–408.Gafurov D., Sturza M.-I., Vavilova E., Magnetic Resonance in Solids 21, 19602 (2019).Gafurov D., Sturza M.-I., Vavilova E., Magnetic Resonance in Solids 21, 19602 (2019).Drechsler S.-L., Volkova O., Vasiliev A. N., Tristan N., Richter J., Schmitt M., Rosner H., M´alek J., Klingeler R., Zvyagin A. A., B¨uchner B., Phys. Rev. Lett. 98, 077202 (2007).Drechsler S.-L., Volkova O., Vasiliev A. N., Tristan N., Richter J., Schmitt M., Rosner H., M´alek J., Klingeler R., Zvyagin A. A., B¨uchner B., Phys. Rev. Lett. 98, 077202 (2007).Hendrickson J. R., Bray P. J., J. Magn. Res. 9, 341 (2007).Hendrickson J. R., Bray P. J., J. Magn. Res. 9, 341 (2007).Arango Y., Electron spin resonance (ESR) spectroscopy of low-dimensional spin systems. PhD dissertation. (TU-Dresden, 2010).Arango Y., Electron spin resonance (ESR) spectroscopy of low-dimensional spin systems. PhD dissertation. (TU-Dresden, 2010).Ruff A., Lunkenheimer P., Krug von Nidda H.-A., Widmann S., Prokofiev A., Svistov L., Loidl A., Krohns S., npj Quantum Mater. 4, 24 (2019).Ruff A., Lunkenheimer P., Krug von Nidda H.-A., Widmann S., Prokofiev A., Svistov L., Loidl A., Krohns S., npj Quantum Mater. 4, 24 (2019).Tokura Y., Seki S., Adv. Mater. 22, 1554–1565 (2010).Tokura Y., Seki S., Adv. Mater. 22, 1554–1565 (2010).Kadomtseva A. M., Zvezdin A. K., Popov Y. F., Pyatakov A. P., Vorob’ev G. P., JETP Letters. 79, 571–581 (2004).Kadomtseva A. M., Zvezdin A. K., Popov Y. F., Pyatakov A. P., Vorob’ev G. P., JETP Letters. 79, 571–581 (2004).Andrzejewski B., Molak A., Hilczer B., Budziak A., Bujakiewicz-Koro´nska R., Journal of Magnetism and Magnetic Materials 342, 17–26 (2013).Andrzejewski B., Molak A., Hilczer B., Budziak A., Bujakiewicz-Koro´nska R., Journal of Magnetism and Magnetic Materials 342, 17–26 (2013).

The authors declare that there are no conflicts of interest present.