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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">mrisel</journal-id><journal-title-group><journal-title xml:lang="en">Magnetic Resonance in Solids</journal-title><trans-title-group xml:lang="ru"><trans-title>Magnetic Resonance in Solids</trans-title></trans-title-group></journal-title-group><issn pub-type="epub">2072-5981</issn><publisher><publisher-name>Kazan Federal University</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.26907/mrsej-21202</article-id><article-id custom-type="elpub" pub-id-type="custom">mrisel-14</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>Modernization of the X-band EPR spectrometer Bruker ElexSys E580 for dynamic nuclear polarization</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Gafurov</surname><given-names>M. R.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kremlevskaya 18, Kazan 42000</p></bio><email xlink:type="simple">marat.gafurov@kpfu.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Mamin</surname><given-names>G. V.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kremlevskaya 18, Kazan 42000</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Zverev</surname><given-names>D. G.</given-names></name></name-alternatives><bio xml:lang="en"><p>Kremlevskaya 18, Kazan 42000</p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>Kazan Federal University</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2021</year></pub-date><pub-date pub-type="epub"><day>12</day><month>12</month><year>2023</year></pub-date><volume>23</volume><issue>2</issue><elocation-id>21202 (6 pp.)</elocation-id><permissions><copyright-statement>Copyright &amp;#x00A9; Gafurov M.R., Mamin G.V., Zverev D.G., 2023</copyright-statement><copyright-year>2023</copyright-year><copyright-holder xml:lang="ru">Gafurov M.R., Mamin G.V., Zverev D.G.</copyright-holder><copyright-holder xml:lang="en">Gafurov M.R., Mamin G.V., Zverev D.G.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.mrsej.ru/jour/article/view/14">https://www.mrsej.ru/jour/article/view/14</self-uri><abstract><p>To study the effects of dynamic nuclear polarization (DNP) in the X-band (microwave frequency of 9 GHz), using the capabilities provided by commercial EPR equipment, a part of the EPR spectrometer associated with the excitation and detection of double electron-nuclear resonance signals (ENDOR) has been modernized. Using the developed preamplifier of NMR signals, a homemade "Kazan Nova II" NMR spectrometer was implemented into the radio frequency path of the EPR spectrometer. The tuning and matching circuits made it possible to observe the NMR and DNP signals on protons in the frequency range 14.5-15.2 MHz. The performance of the DNP equipment was tested for a solution of the stable nitroxyl radical TEMPOL in benzene and a crude oil sample. The DNP effects caused by the Overhauser and solid effects were observed. The modernization of the existing EPR equipment creates a basis for further expanding its capabilities to study DNP effects in various systems at different conditions (in the pulsed mode of saturation of the EPR lines, with the temperature lowering, under the action of optical excitation, etc)</p></abstract><kwd-group xml:lang="en"><kwd>electron paramagnetic resonance</kwd><kwd>nuclear magnetic resonance</kwd><kwd>dynamic nuclear polarization</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The work is financially supported by Russian Science Foundation (grant #19–12–00332)</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Overhauser A.W. Phys. Rev. 92, 411 (1953)</mixed-citation><mixed-citation xml:lang="en">Overhauser A.W. Phys. Rev. 92, 411 (1953)</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Poindexter E. Nature. 182, 1087 (1958)</mixed-citation><mixed-citation xml:lang="en">Poindexter E. Nature. 182, 1087 (1958)</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Can T.V., Ni Q.Z., Griffin R.G. J. Magn. Reson. 253, 23 (2015)</mixed-citation><mixed-citation xml:lang="en">Can T.V., Ni Q.Z., Griffin R.G. J. Magn. Reson. 253, 23 (2015)</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Abhyankar N., Szalai V. The Journal of Physical Chemistry B 125, 5171 (2021)</mixed-citation><mixed-citation xml:lang="en">Abhyankar N., Szalai V. The Journal of Physical Chemistry B 125, 5171 (2021)</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Sapunov V.A., Kashin I.V., Ushakov V.A., Sergeev A.V., Denisova O.V. AIP Conference Proceedings 2174 (2019)</mixed-citation><mixed-citation xml:lang="en">Sapunov V.A., Kashin I.V., Ushakov V.A., Sergeev A.V., Denisova O.V. AIP Conference Proceedings 2174 (2019)</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Chen J., Feng J., Chen F., Zhang Z., Chen L., Liao R., Liu M., Liu C., Fuel 1257 , 116107 (2019)</mixed-citation><mixed-citation xml:lang="en">Chen J., Feng J., Chen F., Zhang Z., Chen L., Liao R., Liu M., Liu C., Fuel 1257 , 116107 (2019)</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Alexandrov A. S., Archipov R. V., Ivanov A. A., Gnezdilov O. I., Gafurov M. R., Skirda V. D. Applied Magnetic Resonance 45, 1275 (2014)</mixed-citation><mixed-citation xml:lang="en">Alexandrov A. S., Archipov R. V., Ivanov A. A., Gnezdilov O. I., Gafurov M. R., Skirda V. D. Applied Magnetic Resonance 45, 1275 (2014)</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Peksoz A., Almaz E., Yalciner A. J. Petrol. Sci. Eng. 75, 58 (2010)</mixed-citation><mixed-citation xml:lang="en">Peksoz A., Almaz E., Yalciner A. J. Petrol. Sci. Eng. 75, 58 (2010)</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Ivanov D.S., Barskaya E.E., Skirda V.D. Magn. Reson. Solids 21, 19201 (2019)</mixed-citation><mixed-citation xml:lang="en">Ivanov D.S., Barskaya E.E., Skirda V.D. Magn. Reson. Solids 21, 19201 (2019)</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Ivanov D.S., Barskaya E.E., Skirda V.D. Magn. Reson. Solids 21, 19202 (2019)</mixed-citation><mixed-citation xml:lang="en">Ivanov D.S., Barskaya E.E., Skirda V.D. Magn. Reson. Solids 21, 19202 (2019)</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Gafurov M.R., Ponomarev A.A., Mamin G.V., Rodionov A.A., Murzakhanov F.F., Arash T., Orlinskii S.B. Georesursy ( Georesources) 22, No. 4, 2 (2020)</mixed-citation><mixed-citation xml:lang="en">Gafurov M.R., Ponomarev A.A., Mamin G.V., Rodionov A.A., Murzakhanov F.F., Arash T., Orlinskii S.B. Georesursy ( Georesources) 22, No. 4, 2 (2020)</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Alexandrov A.S., Ivanov A.A., Archipov R.V., Gafurov M.R., Tagirov M.S Magn. Reson. Solids 21, 19203 (2019)</mixed-citation><mixed-citation xml:lang="en">Alexandrov A.S., Ivanov A.A., Archipov R.V., Gafurov M.R., Tagirov M.S Magn. Reson. Solids 21, 19203 (2019)</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Davydov V.V., Myazin N.S., Grebenikova N.M., Dudkin V.I. Measurement Techniques 62, 1090 (2020)</mixed-citation><mixed-citation xml:lang="en">Davydov V.V., Myazin N.S., Grebenikova N.M., Dudkin V.I. Measurement Techniques 62, 1090 (2020)</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Davydov V. V., Dudkin V.I., Vysoczky M.G., Myazin N.S. Applied Magnetic Resonance 51, 653 (2020)</mixed-citation><mixed-citation xml:lang="en">Davydov V. V., Dudkin V.I., Vysoczky M.G., Myazin N.S. Applied Magnetic Resonance 51, 653 (2020)</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Gizatullin B., Gafurov M., Vakhin A., Rodionov A., Mamin G., Orlinskii S., Mattea C., Stapf S. Energy and Fuels 33, 10923 (2019)</mixed-citation><mixed-citation xml:lang="en">Gizatullin B., Gafurov M., Vakhin A., Rodionov A., Mamin G., Orlinskii S., Mattea C., Stapf S. Energy and Fuels 33, 10923 (2019)</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Gizatullin B., Gafurov M., Murzakhanov F., Vakhin A., Mattea C. and Stapf S. Langmuir 37, 6783 (2021)</mixed-citation><mixed-citation xml:lang="en">Gizatullin B., Gafurov M., Murzakhanov F., Vakhin A., Mattea C. and Stapf S. Langmuir 37, 6783 (2021)</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Khusnutdinov R.R., Mukhamedshin I.R., Mamin G.V. 2018 XIV International ScientificTechnical Conference on Actual Problems of Electronics Instrument Engineering (APEIE) 174, (2018)</mixed-citation><mixed-citation xml:lang="en">Khusnutdinov R.R., Mukhamedshin I.R., Mamin G.V. 2018 XIV International ScientificTechnical Conference on Actual Problems of Electronics Instrument Engineering (APEIE) 174, (2018)</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Gafurov M.R. Magn. Reson. Solids 15, 13103 (2013)</mixed-citation><mixed-citation xml:lang="en">Gafurov M.R. Magn. Reson. Solids 15, 13103 (2013)</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Gizatullin B., Mattea C., Stapf S. Journal of Magnetic Resonance 307, 106583 (2019)</mixed-citation><mixed-citation xml:lang="en">Gizatullin B., Mattea C., Stapf S. Journal of Magnetic Resonance 307, 106583 (2019)</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Neudert O., Mattea C., Stapf S. Journal of Magnetic Resonance 271, 7 (2016)</mixed-citation><mixed-citation xml:lang="en">Neudert O., Mattea C., Stapf S. Journal of Magnetic Resonance 271, 7 (2016)</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Leblond J., Uebersfeld J., Korringa J. Phys. Rev. A 4, 1532 (1971)</mixed-citation><mixed-citation xml:lang="en">Leblond J., Uebersfeld J., Korringa J. Phys. Rev. A 4, 1532 (1971)</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
