mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal Universitymrisel-128Research ArticleСтатьиCrystal field parameters and g-factors of the ground Kramers doublet of Ce3+ ion in LiYF4 crystalSolovyevO. V.

Kremlevskaya 18, Kazan 420008

Oleg.Solovyev@mail.ruKazan Federal UniversityRussian Federation20151912201517115103 (8 pp.)Copyright © Solovyev O.V., 20242024Solovyev O.V.Solovyev O.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/128

Analytical expressions are obtained for g-factors of the ground Kramers doublet of the impurity Ce3+ ions in LiYF4 crystal that rigorously take into account mixing of the 2F5/2 and 2F7/2 multiplets by crystal field. Dependence of g-factors on crystal field parameters is studied and possibilities of making conclusions about crystal filed parameters values on the basis of comparison with g-factors given in literature are considered.

crystal field parametersg-factorsLiYF4:Ce3+The work is performed according to the Russian Government Program of Competitive Growth of Kazan Federal University and the RFBR Grant 14-02-00826.ReferencesAminov L.K., Ershova A.A., Efimov V.N., Korableva S.L., Kurkin I.N., Malkin B.Z., Rodionov A.A. Phys. Solid State 52, 2070 (2010) (Fizika Tverdogo Tela 52, 1931 (2010), in Russian)Aminov L.K., Ershova A.A., Efimov V.N., Korableva S.L., Kurkin I.N., Malkin B.Z., Rodionov A.A. Phys. Solid State 52, 2070 (2010) (Fizika Tverdogo Tela 52, 1931 (2010), in Russian)Yosida T., Yamaga M., Lee D., Han T.P.J., Gallagher H.G., Henderson B. J. Phys.: Condens. Matter 9, 3733 (1997)Yosida T., Yamaga M., Lee D., Han T.P.J., Gallagher H.G., Henderson B. J. Phys.: Condens. Matter 9, 3733 (1997)Kutuzov A.S., Skvortsova A.M. Magn. Reson. Solids 11, 7 (2009)Kutuzov A.S., Skvortsova A.M. Magn. Reson. Solids 11, 7 (2009)Malkin B.Z., Solovyev O.V., Malishev A.Yu., Saikin S.K. J. Lumin. 125, 175 (2007)Malkin B.Z., Solovyev O.V., Malishev A.Yu., Saikin S.K. J. Lumin. 125, 175 (2007)Abragam A., Bleany B. Electron Paramagnetic Resonance of Transition Ions, Clarendon Press, Oxford (1970)Abragam A., Bleany B. Electron Paramagnetic Resonance of Transition Ions, Clarendon Press, Oxford (1970)Van Pieterson L., Reid M.F., Wegh R.T., Soverna S., Meijerink A. Phys. Rev. B 65, 045113 (2002)Van Pieterson L., Reid M.F., Wegh R.T., Soverna S., Meijerink A. Phys. Rev. B 65, 045113 (2002)Malkin B.Z., in Spectroscopy of Solids Containing Rare-Earth Ions, edited by A.A. Kaplyanskii and R.M. Macfarlane (North-Holland, Amsterdam, 1987), p. 13Malkin B.Z., in Spectroscopy of Solids Containing Rare-Earth Ions, edited by A.A. Kaplyanskii and R.M. Macfarlane (North-Holland, Amsterdam, 1987), p. 13Peijzel P.S., Vergeer P., Meijerink A., Reid M.F., Boatner L.A., Burdick G.W. Phys. Rev. B 71, 045116 (2005)Peijzel P.S., Vergeer P., Meijerink A., Reid M.F., Boatner L.A., Burdick G.W. Phys. Rev. B 71, 045116 (2005)Shannon R.D., Acta Crystallogr. A. 32, 751 (1976)Shannon R.D., Acta Crystallogr. A. 32, 751 (1976)

The authors declare that there are no conflicts of interest present.