mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal Universitymrisel-126Research ArticleСтатьиSize-dependent concentration of N0 paramagnetic centres in HPHT nanodiamondsYavkinB. V.

Kremlevskaya 18, Kazan 420008

boris.yavkin@gmail.comMaminG. V.

Kremlevskaya 18, Kazan 420008

GafurovM. R.

Kremlevskaya 18, Kazan 420008

OrlinskiiS. B.

Kremlevskaya 18, Kazan 420008

Kazan Federal UniversityRussian Federation20151112201517115101 (7 pp.)Copyright © Yavkin B.V., Mamin G.V., Gafurov M.R., Orlinskii S.B., 20242024Yavkin B.V., Mamin G.V., Gafurov M.R., Orlinskii S.B.Yavkin B.V., Mamin G.V., Gafurov M.R., Orlinskii S.B.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/126

Size-calibrated commercial nanodiamonds synthesized by high-pressure high-temperature (HPHT) technique were studied by high-frequency W- and conventional X-band electron paramagnetic resonance (EPR) spectroscopy. The numbers of spins in the studied samples were estimated. The core-shell model of the HPHT nanodiamonds was proposed to explain the observed dependence of the concentration of the N0 paramagnetic centers. Two other observed paramagnetic centers are attributed to the two types of structures in the nanodiamond shell.

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The authors declare that there are no conflicts of interest present.