mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal Universitymrisel-122Research ArticleСтатьиLithium diffusion in a new cathode material Li0.8[Ni0.6Sb0.4]O2 studied by 7Li NMRSalikhovT.

Sibirskii trakt 10/7, Kazan 420029

tmsalikhov@gmail.comKlyshevaE.

Sibirskii trakt 10/7, Kazan 420029

ZverevaE.

Leninskie Gory 1-2, Moscow 119991

NalbandyanV.

Sorge 7, Rostov-on-Don 344090

ShukaevI.

Sorge 7, Rostov-on-Don 344090

MedvedevB.

Sorge 7, Rostov-on-Don 344090

VavilovaE.

Sibirskii trakt 10/7, Kazan 420029

Zavoisky Physical-Technical Institute of RASRussian FederationFaculty of Physics, Moscow State UniversityRussian FederationChemistry Faculty, Southern Federal UniversityRussian Federation20161812201618216207 (8 pp.)Copyright © Salikhov T., Klysheva E., Zvereva E., Nalbandyan V., Shukaev I., Medvedev B., Vavilova E., 20242024Salikhov T., Klysheva E., Zvereva E., Nalbandyan V., Shukaev I., Medvedev B., Vavilova E.Salikhov T., Klysheva E., Zvereva E., Nalbandyan V., Shukaev I., Medvedev B., Vavilova E.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/122

A rhombohedral layered α-NaFeO2-type compound, Lix[Ni(1+x)/3Sb(2-x)/3]O2 (x=0.8) has been prepared from the sodium analogue by ion exchange at 570 K. In contrast to the stoichiometric composition Li3Ni2SbO6, it shows considerable Li/Ni inversion and no long-range Ni/Sb ordering. The temperature dependence of the 7Li NMR spin-lattice relaxation rate and linewidth data measured at temperature range from 30-450 K show the sharp increase of lithium ions mobility comparing to the stoichiometric compound Li3Ni2SbO6. From the NMR data the activation energy was estimated by different methods.

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The authors declare that there are no conflicts of interest present.