mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal Universitymrisel-121Research ArticleСтатьиStudy of the crystal field in CeF3 and CeF3:Pr3+ShafikovF. F.

Kremlevskaya 18, Kazan 420008

SavinkovA. V.

Kremlevskaya 18, Kazan 420008

Andrey.Savinkov@gmail.comTagirovM. S.

Kremlevskaya 18, Kazan 420008; L. Bulachnaya 36a, Kazan 420111

Kazan Federal UniversityRussian FederationKazan Federal University; Institute of Perspective Research, TASRussian Federation20161812201618216206 (5 pp.)Copyright © Shafikov F.F., Savinkov A.V., Tagirov M.S., 20242024Shafikov F.F., Savinkov A.V., Tagirov M.S.Shafikov F.F., Savinkov A.V., Tagirov M.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/121

The crystal field analysis based on calculations in the framework of the semi phenomenological exchange charge model was carried out. The set of crystal field parameters for Ce3+ and Pr3+ ions in the matrix CeF3 related to the crystallographic system of coordinates has been obtained and used to reproduce satisfactory the crystal field energies of Ce3+ and Pr3+ ions.

crystal field parametersexchange charge modeltrifluoridesThe work is performed according to the Russian Government Program of Competitive Growth of Kazan Federal University, partly supported by the Russian Foundation for Basic Research (Project No.15-02-06990_а).ReferencesSavinkov A.V., Irisov D.S., Malkin B.Z., Safiullin K.R., Suzuki H., Tagirov M.S., Tayurskii D.A. J. Phys.: Condens. Matter 18, 6337 (2006)Savinkov A.V., Irisov D.S., Malkin B.Z., Safiullin K.R., Suzuki H., Tagirov M.S., Tayurskii D.A. J. Phys.: Condens. Matter 18, 6337 (2006)Liu G., Yuan B., Zhang N., Gong X. J. Appl. Phys. 78, 4054 (1995)Liu G., Yuan B., Zhang N., Gong X. J. Appl. Phys. 78, 4054 (1995)Savinkov A.V., Korableva S.L., Rodionov A.A., Kurkin I.N., Malkin B.Z., Tagirov M.S., Suzuki H., Matsumoto K., Abe S. J. Phys.: Condens. Matter 20, 485220 (2008)Savinkov A.V., Korableva S.L., Rodionov A.A., Kurkin I.N., Malkin B.Z., Tagirov M.S., Suzuki H., Matsumoto K., Abe S. J. Phys.: Condens. Matter 20, 485220 (2008)Yu L., Song H., Liu Zh., Yang L., Lu Sh., Zheng Zh. Solid State Commun. 134, 753 (2005)Yu L., Song H., Liu Zh., Yang L., Lu Sh., Zheng Zh. Solid State Commun. 134, 753 (2005)Bu W., Hua Z., Chen H., Shi J. J. Phys. Chem. B 109, 14461 (2005)Bu W., Hua Z., Chen H., Shi J. J. Phys. Chem. B 109, 14461 (2005)Guo H. Appl. Phys. B 84, 365 (2006)Guo H. Appl. Phys. B 84, 365 (2006)Wang Z.L., Quan Z.W., Jia P.Y., Lin C.K., Luo Y., Chen Y., Fang J., Zhou W., O’Connor C.J., Lin J. Chem. Mater. 18, 2030 (2006)Wang Z.L., Quan Z.W., Jia P.Y., Lin C.K., Luo Y., Chen Y., Fang J., Zhou W., O’Connor C.J., Lin J. Chem. Mater. 18, 2030 (2006)Grzyb T., Lis S. J. Rare Earths 27, 588 (2009)Grzyb T., Lis S. J. Rare Earths 27, 588 (2009)Gerlinger H., Schaack G. Phys. Rev. B 33, 7438 (1986)Gerlinger H., Schaack G. Phys. Rev. B 33, 7438 (1986)Petrov K.I., Sharipov Kh.T., Sinitsyn B.V., Shakhkalamyan G.S. Zhurnal Prikladnoi Spectroskopii 17, 823 (1972) (in Russian)Petrov K.I., Sharipov Kh.T., Sinitsyn B.V., Shakhkalamyan G.S. Zhurnal Prikladnoi Spectroskopii 17, 823 (1972) (in Russian)Maximov B., Schulz H. Acta Cryst. B 41, 88 (1985)Maximov B., Schulz H. Acta Cryst. B 41, 88 (1985)Dahl M., Schaack G.Z. Phys. B 56, 279 (1984)Dahl M., Schaack G.Z. Phys. B 56, 279 (1984)Zalkin A., Templeton D.H. Acta Crystallogr. B 41, 91 (1985)Zalkin A., Templeton D.H. Acta Crystallogr. B 41, 91 (1985)Batsanova L.R. Uspekhi Khimii 40, 945 (1971) (in Russian)Batsanova L.R. Uspekhi Khimii 40, 945 (1971) (in Russian)Freeman A.J., Watson R.E. Phys. Rev. 127, 2058 (1962)Freeman A.J., Watson R.E. Phys. Rev. 127, 2058 (1962)Malkin B.Z. Spectroscopy of Solids Containing Rare-Earth Ions, ed. Kaplyanskii A.A. and Macfarlane R.M. (Elsevier, Amsterdam, 1987) pp. 13-49Malkin B.Z. Spectroscopy of Solids Containing Rare-Earth Ions, ed. Kaplyanskii A.A. and Macfarlane R.M. (Elsevier, Amsterdam, 1987) pp. 13-49Carnall W.T., Goodman G.L., Rajnak K., Rana R.S. J. Chem. Phys. 90, 3444 (1989)Carnall W.T., Goodman G.L., Rajnak K., Rana R.S. J. Chem. Phys. 90, 3444 (1989)

The authors declare that there are no conflicts of interest present.