mriselMagnetic Resonance in SolidsMagnetic Resonance in Solids2072-5981Kazan Federal Universitymrisel-103Research ArticleСтатьиSpectral and magnetic properties of impurity Tm3+ ions in YF3SavinkovA. V.

Kremlevskaya 18, Kazan 420008

Andrey.Savinkov@gmail.comShakurovG. S.

Sibirskiy trakt 10/7, Kazan 420029

MumdzhiI. E.

Kremlevskaya 18, Kazan 420008

MalkinB. Z.

Kremlevskaya 18, Kazan 420008

NikitinS. I.

Kremlevskaya 18, Kazan 420008

KorablevaS. I.

Kremlevskaya 18, Kazan 420008

TagirovM. S.

Kremlevskaya 18, Kazan 420008; L. Bulachnaya 36a, Kazan 420111

Kazan Federal UniversityRussian FederationKazan Physical-Technical InstituteRussian FederationKazan Federal University; Institute of Perspective Research, TASRussian Federation20170512201719217202 (7 pp.)Copyright © Savinkov A.V., Shakurov G.S., Mumdzhi I.E., Malkin B.Z., Nikitin S.I., Korableva S.I., Tagirov M.S., 20242024Savinkov A.V., Shakurov G.S., Mumdzhi I.E., Malkin B.Z., Nikitin S.I., Korableva S.I., Tagirov M.S.Savinkov A.V., Shakurov G.S., Mumdzhi I.E., Malkin B.Z., Nikitin S.I., Korableva S.I., Tagirov M.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.mrsej.ru/jour/article/view/103

Stark structure of 3H6, 3H5, 3H4, 3F4, 3F3, 3F2 and 1G4 multiplets of impurity non-Kramers Tm3+ ions in the orthorhombic YF3 crystal has been determined from luminescence studies. High frequency electron paramagnetic resonance (EPR) spectra (~ 207 GHz) of Tm3+ ions have been measured at temperature 4.2 K in external magnetic field applied perpendicular to the b-axis of YF3:Tm3+ single crystal. The results of measurements are interpreted in the frameworks of the crystal field theory. The set of crystal field parameters related to the crystallographic system of coordinates of the YF3 lattice has been obtained and used to reproduce satisfactory the crystal field energies and the EPR spectra.

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The authors declare that there are no conflicts of interest present.